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101.
提出了一种在小波包分析对吸收光谱数据进行降噪处理的基础上,采用线性插值增加校正样样本数的新思路,为解决多组分分光光度同时测定中经常遇到的样本少变量多的问题,对提高预测结果的准确性提供了一种新方法。应用小波包分析-一维线性插值-RBF网络处理铝合金样品中铁、锰、铜、锌的同时测定。由于小波包分析-线性插值处理既能发挥良好的滤噪作用,又能使训练集样本对待辩识空间形成较好的覆盖,从而使RBF网络能提取到更多的特征信息,改善网络性能,研究结果表明,该方法可以显著降低测定样的相对误差,获得的测定结果令人满意。 相似文献
102.
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104.
Studies on heteronuclear diatomic molecular dissociation energies using algebraic energy method 总被引:1,自引:0,他引:1 下载免费PDF全文
The algebraic energy method (AEM) is applied to the study of
molecular dissociation energy $D_e$ for 11 heteronuclear diatomic
electronic states: $a^3\Sigma^+$ state of NaK, $X^2\Sigma^+$ state
of XeBr, $X^2\Sigma^+$ state of HgI, $X^1\Sigma^+$ state of LiH,
$A^3\Pi(1)$ state of ICl, $X^1\Sigma^+$ state of CsH, $A(^3\Pi_1)$
and $B0^+(^3\Pi)$ states of ClF, $2^1\Pi$ state of KRb,
$X^1\Sigma^+$ state of CO, and $c^3\Sigma^+$ state of NaK molecule.
The results show that the values of $D_e$ computed by using the AEM
are satisfactorily accurate compared with experimental ones. The AEM
can serve as an economic and useful tool to generate a reliable
$D_e$ within an allowed experimental error for the electronic states
whose molecular dissociation energies are unavailable from the
existing literature. 相似文献
105.
A new improved nuclear partition function is employed to calculate
the nuclear statistical equilibrium (NSE) in core-collapse supernova
environment. The results show that the change of nucleus abundance
is slight even though the temperature is higher than 10$^{11}$\,K
when shock propagates, which indicates that the effect of the
nuclear partition function is not so important as shown in the
previous calculations, but it can also be considered in detailed
simulation if it is sensitive to weak interaction rates in
core-collapse supernova. 相似文献
106.
对乙酰氨基酚在活化玻碳电极上的电化学行为及测定 总被引:2,自引:0,他引:2
应用循环伏安法,研究了对乙酰氨基酚(PCT)在活化玻碳电极上的电化学行为.在pH=4.00的HAc-NaAc缓冲溶液中,PCT的CV扫描于0.54 V左右出现一对明显的氧化-还原峰.电极反应为2电子、2质子的受吸附控制的准可逆过程.其氧化峰电流与PCT浓度在8.00×10-6~2.00×10-4mol.L-1范围内呈良好的线性关系,相关系数r=-0.99918;检出限为6.34×10-6mol.L-1.用于药物样品PCT的含量测定,结果满意. 相似文献
107.
In this paper, firstly, we investigate the neutrino
emissivity from quark Urca process in strong magnetic field. Then, we
discuss the heat capacity of strange stars in strong magnetic field.
Finally, we give the cooling curve in strong magnetic field. In order to
make a comparison, we also give the corresponding cooling curve in the case
of null magnetic field. It turns out that strange stars cool faster
in strong magnetic field than that without magnetic field. 相似文献
108.
109.
求出了(n-3)-filiform李代数的极大环面,并证明了(n-3)-filiform李代数是可完备化的. 相似文献
110.
Prof. Dr. Haifang Mao Manli Guo Hongqing Fu Dr. Kun Yin Dr. Miaomiao Jin Chaoyang Wang Prof. Dr. Yun Zhao Dr. Zhenbiao Dong Dr. Jibo Liu 《欧洲无机化学杂志》2023,26(4):e202200624
Aiming highly efficient conversion of greenhouse gas CO2 to cyclic carbonates, a biomass Ru(III) Schiff base complex catalyst ( SalRu ) was constructed by employing a derivative of Lignin degradation (5-aldehyde vanillin). The SalRu catalyst had a remarkable conversion for epoxides into corresponding cyclic carbonates even at atmospheric pressure of CO2 without the presence of co-catalyst. As the condition at 120 °C and 2 MPa CO2 the conversion reached to 94 % with selectivity at 99 % after 8 h. 32 % cyclic carbonate production was obtained even under 0.2 MPa CO2 pressure. The epoxide activation and ring opening, CO2 insertion and cyclic carbonate formation were illuminated explicitly through the of characteristic absorption peaks changing, which further providing direct and visual evidence for the mechanism proposing. This study has important theoretical significance for the comprehensive utilization of environmental pollutants and energy. 相似文献